Ethylenediammonium bis[Copper(II) Monohydrogendiphosphate Ethylenediamine] Trihydrate
Identifieur interne : 000297 ( France/Analysis ); précédent : 000296; suivant : 000298Ethylenediammonium bis[Copper(II) Monohydrogendiphosphate Ethylenediamine] Trihydrate
Auteurs : A. Gharbi [France] ; A. Jouini [France] ; M. T. Averbuch-Pouchot [France] ; A. Durif [France]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1994.
Abstract
Abstract: Chemical preparation, calorimetric studies, crystal structure, and IR absorption spectra are given for a new metal-organic diphosphate. From a structural point of view the title compound Cu2(C2N2H10)(HP2O7)2(C2N2H8)2 · 3H2O is an intricate stacking of copper(II) atoms, ethylenediammonium groups, HP2O4-7 anions, and both ethylenediamine and water molecules. This layered arrangement has a monoclinic unit cell with a = 18.808(8) Å, b = 9.631(2) Å, c = 14.019(8) Å, and β = 109.63(5)°. The space group is C2/c and z = 4. As in all atomic arrangements including acidic diphosphate groups one observes the formation of an infinite network of anions connected by strong H-bonds, infinite (HP2O7)n chains parallel to the b direction, for the present structure. The copper atom has a square-pyramidal fivefold coordination built by two nitrogen atoms, two oxygen atoms, and one water molecule. Another interesting feature of the title compound is the coexistence of both ethylenediammonium groups and ethylenediamine molecules in the atomic arrangement. A chelated complex of the formula [Cu(C2H8N2)(HP2O7)(H2O)]- is observed.
Url:
DOI: 10.1006/jssc.1994.1235
Affiliations:
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Fourier, BP 166. 38042, Grenoble Cedex 09</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Averbuch Pouchot, M T" sort="Averbuch Pouchot, M T" uniqKey="Averbuch Pouchot M" first="M. T." last="Averbuch-Pouchot">M. T. Averbuch-Pouchot</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie, du Solide, Département de Chimie, Faculté des Sciences, Université du Centre, Monastir 5000, Tunisia and Laboratoire de, Cristallographie, CNRS, Associé à l'Université J. Fourier, BP 166. 38042, Grenoble Cedex 09</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Durif, A" sort="Durif, A" uniqKey="Durif A" first="A." last="Durif">A. Durif</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie, du Solide, Département de Chimie, Faculté des Sciences, Université du Centre, Monastir 5000, Tunisia and Laboratoire de, Cristallographie, CNRS, Associé à l'Université J. Fourier, BP 166. 38042, Grenoble Cedex 09</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Solid State Chemistry</title><title level="j" type="abbrev">YJSSC</title><idno type="ISSN">0022-4596</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1994">1994</date><biblScope unit="volume">111</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="330">330</biblScope><biblScope unit="page" to="337">337</biblScope></imprint><idno type="ISSN">0022-4596</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: Chemical preparation, calorimetric studies, crystal structure, and IR absorption spectra are given for a new metal-organic diphosphate. From a structural point of view the title compound Cu2(C2N2H10)(HP2O7)2(C2N2H8)2 · 3H2O is an intricate stacking of copper(II) atoms, ethylenediammonium groups, HP2O4-7 anions, and both ethylenediamine and water molecules. This layered arrangement has a monoclinic unit cell with a = 18.808(8) Å, b = 9.631(2) Å, c = 14.019(8) Å, and β = 109.63(5)°. The space group is C2/c and z = 4. As in all atomic arrangements including acidic diphosphate groups one observes the formation of an infinite network of anions connected by strong H-bonds, infinite (HP2O7)n chains parallel to the b direction, for the present structure. The copper atom has a square-pyramidal fivefold coordination built by two nitrogen atoms, two oxygen atoms, and one water molecule. Another interesting feature of the title compound is the coexistence of both ethylenediammonium groups and ethylenediamine molecules in the atomic arrangement. A chelated complex of the formula [Cu(C2H8N2)(HP2O7)(H2O)]- is observed.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Auvergne-Rhône-Alpes</li><li>Rhône-Alpes</li></region><settlement><li>Grenoble</li></settlement></list><tree><country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Gharbi, A" sort="Gharbi, A" uniqKey="Gharbi A" first="A." last="Gharbi">A. Gharbi</name></region><name sortKey="Averbuch Pouchot, M T" sort="Averbuch Pouchot, M T" uniqKey="Averbuch Pouchot M" first="M. T." last="Averbuch-Pouchot">M. T. Averbuch-Pouchot</name><name sortKey="Durif, A" sort="Durif, A" uniqKey="Durif A" first="A." last="Durif">A. Durif</name><name sortKey="Jouini, A" sort="Jouini, A" uniqKey="Jouini A" first="A." last="Jouini">A. Jouini</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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